Petrochronology of oxidized granulites from southern Peru

Sapphirine–quartz granulites from the Cocachacra region of the Arequipa Massif in southern Peru record early Neoproterozoic ultrahigh‐temperature metamorphism. Phase equilibrium modelling and zircon petrochronology are used to quantify timing and pressure–temperature (P–T) conditions of metamorphism. Modelling of three magnetite‐bearing sapphirine–quartz samples indicates peak temperatures of >950°C at ~0.7 GPa and a clockwise P–T evolution. Elevated concentrations of Al in orthopyroxene are also consistent with ultrahigh‐temperature conditions. Neoblastic zircon records ages of c. 1.0–0.9 Ga that are interpreted to record protracted ultrahigh‐temperature metamorphism. Th/U ratios of zircon of up to 100 reflect U‐depleted whole‐rock compositions. Concentrations of heavy rare earth elements in zircon do not show systematic trends with U–Pb age but do correlate with variable whole‐rock compositions. Very large positive Ce anomalies in zircon from two samples probably relate to strongly oxidizing conditions during neoblastic zircon crystallization. Low concentrations of Ti‐in‐zircon (<10 ppm) are interpreted to result from reduced titania activities due to the strongly oxidized nature of the granulites and the sequestration of titanium‐rich minerals away from the reaction volume. Whole‐rock compositions and oxidation state have a strong influence on the trace element composition of metamorphic zircon, which has implications for interpreting the geological significance of ages retrieved from zircon in oxidized metamorphic rocks.     

Otolith microchemistry indicates regional phylopatry in the larval phase of an amphidromous fish (Gobiomorphus hubbsi)

Knowledge of stock structure is key for the effective management of any fish species. Amphidromous fish, which live and spawn in freshwater but spend a pelagic larval period at sea, have typically been assumed to disperse widely during their larval phase, resulting in populations being sourced from a single unstructured larval pool. We used otolith microchemical analysis to examine the stock structure of bluegill bully (Gobiomorphus hubbsi), a declining amphidromous eleotrid endemic to New Zealand, along the west coast of South Island, New Zealand. Some drainages – even those in close proximity (c. 20?km) – were readily distinguishable based on otolith trace element concentrations, while little structure was evident between other geographically disparate locations. These results indicate that, at least in some cases, locally retained larvae, rather than a single unstructured larval pool, dominates recruitment. Management of bluegill bully and other amphidromous species must therefore consider the possibility of regionally distinct populations.     

Zircon U–Pb age, trace element and Hf isotope composition of Kongling terrane in the Yangtze Craton: refining the timing of Palaeoproterozoic high-grade metamorphism

U–Pb age, trace element and Hf isotope compositions of zircon were analysed for a metasedimentary rock and two amphibolites from the Kongling terrane in the northern part of the Yangtze Craton. The zircon shows distinct morphological and chemical characteristics. Most zircon in an amphibolite shows oscillatory zoning, high Th/U and ¹⁷⁶Lu/¹⁷⁷Hf ratios, high formation temperature, high trace element contents, clear negative Eu anomaly, as well as HREE-enriched patterns, suggesting that it is igneous. The zircon yields a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2857 ± 8 Ma, representing the age of the magmatic protolith. The zircon in the other two samples is metamorphic. It has low Th/U ratios, low trace element concentrations, variable HREE contents (33.8 ≥ Lu_N≥2213; 14.7 ≤ Lu_N/Sm_N ≤ 354) and ¹⁷⁶Lu/¹⁷⁷Hf ratios (0.000030–0.001168). The data indicate that the zircon formed in the presence of garnet and under upper amphibolite facies conditions. The metamorphic zircon yields a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2010 ± 13 Ma. These results combined with previously obtained Palaeoproterozoic metamorphic ages suggest a c. 2.0 Ga Palaeoproterozoic collisional event in the Yangtze Craton, which may result from the assembly of the supercontinent Columbia. The zircon in two samples yields weighted mean two-stage Hf model ( T _DM2) ages of 3217 ± 110 and 2943 ± 50 Ma, respectively, indicating that their protoliths were mainly derived from Archean crust.     

Effect of metamorphism and partial melting of host rocks on zircons

Abstract Zircons have been studied from different layers of migmatites (from Arvika, western Sweden and Nelaug, southern Norway) and from a paragneiss (from Arvika) associated with one of the migmatites. The main purpose of the investigation is to establish whether or not information about zircons can help in the elucidation of the parentage and rock-forming processes of migmatites.
The elongation ratio of zircons from all layers is small and characteristic of sedimentary zircons. Further, the absence of characteristic colours and the growth trends of the zircons (indicated by the reduced major axes) observed in the various samples both support a sedimentary parentage for these rocks. The zircons of all layers exhibit secondary growth (overgrowth, outgrowth and multiple growth) due to metamorphism. Compared with the zircons from the paragneiss, those of the migmatite layers are more clouded and less rounded, some of them becoming opaque or even skeletal; this is especially true of the zircons from the leucosomes. These observations indicate an alteration of the original sedimentary zircons in the migmatite, especially in the leucosomes, in response to the migmatization process, previously interpreted as partial melting.     

Ionprobe U-Pb zircon ages from the high-pressure/low-temperature mélange of Syros, Greece: age diversity and the importance of pre-Eocene subduction

The Cycladic blueschist belt in the central Aegean Sea has experienced high‐pressure (HP) metamorphism during collisional processes between the Apulian microplate and Eurasia. The general geological and tectonometamorphic framework is well documented, but one aspect which is yet not sufficiently explored is the importance of HP mélanges which occur within volcano‐sedimentary successions. Unresolved issues concern the range in magmatic and metamorphic ages recorded by mélange blocks and the significance of eventual pre‐Eocene HP metamorphism. These aspects are here addressed in a U‐Pb zircon study focusing on the block–matrix association exposed on the island of Syros. Two gneisses from a tectonic slab of this mélange, consisting of an interlayered felsic gneiss‐glaucophanite sequence, yielded zircon ²⁰⁶Pb/²³⁸U ages of 240.1 ± 4.1 and 245.3 ± 4.9 Ma, respectively, similar to Triassic ages determined on zircon in meta‐volcanic rocks from structurally coherent sequences elsewhere in the Cyclades. This strongly suggests that parts of these successions have been incorporated in the mélanges and provides the first geochronological evidence that the provenance of mélange blocks/slabs is neither restricted to a single source nor confined to fragments of oceanic lithosphere. Zircon from a jadeitite and associated alteration zones (omphacitite, glaucophanite and chlorite‐actinolite rock) all yielded identical ²⁰⁶Pb/²³⁸U ages of c. 80 Ma. Similar Cretaceous U‐Pb zircon ages previously reported for mélange blocks have been interpreted by different authors to reflect magmatic or metamorphic ages. The present study adds a further argument in favour of the view that zircon formed newly in some rock types at c. 80 Ma, due to hydrothermal or metasomatic processes in a subduction zone environment, and supports the interpretation that the Cycladic blueschist belt records both Cretaceous and Eocene HP episodes and not only a single Tertiary HP event.     

西藏结则茶卡湖岸沉积物中铀系年龄及意义

通过对藏北高原西北部结则茶卡湖泊及其沿岸地质地貌调查,发现其为一个富含硼、锂、钾、锶的封闭型盐湖,沿岸海拔4 850 m拔湖325 m有一条明显的高位湖岸线,该湖岸线到湖面之间有六级湖积阶地发育,六级以上阶地保存零星。沿湖岸不同高度上的湖积物U系年龄分别为(14.2±1.2)ka BP(T2)、(38.0±3.5)ka BP(T4)和(41.6±3.2)ka BP(T5)。湖面下降的幅度是藏北高原迄今所知最大。根据湖面平均下降速度推算高位湖岸线和高位湖积层的形成年龄在(120~90)ka BP,与东部的纳木错和西部的甜水海基本一致,说明藏北高原在晚更新世初期有一个明显的泛湖期。大约100 ka BP结则茶卡湖面开始下降,晚更新世以来湖泊演化是在封闭体系干旱环境下进行的,盐湖形成于14 ka BP左右,藏北高原在晚更新世以来气候变化可能为自西向东逐渐变为干寒。     

Pan-African eclogite facies metamorphism of ultramafic rocks in the Shackleton Range, Antarctica

In the Shackleton Range of East Antarctica, garnet-bearing ultramafic rocks occur as lenses in supracrustal high-grade gneisses. In the presence of olivine, garnet is an unmistakable indicator of eclogite facies metamorphic conditions. The eclogite facies assemblages are only present in ultramafic rocks, particularly in pyroxenites, whereas other lithologies – including metabasites – lack such assemblages. We conclude that under high-temperature conditions, pyroxenites preserve high-pressure assemblages better than isofacial metabasites, provided the pressure is high enough to stabilize garnet–olivine assemblages (i.e. ≥18–20 kbar). The Shackleton Range ultramafic rocks experienced a clockwise P–T path and peak conditions of 800–850 °C and 23–25 kbar. These conditions correspond to ∼70 km depth of burial and a metamorphic gradient of 11–12 °C km⁻¹ that is typical of a convergent plate-margin setting. The age of metamorphism is defined by two garnet–whole-rock Sm–Nd isochrons that give ages of 525 ± 5 and 520 ± 14 Ma corresponding to the time of the Pan-African orogeny. These results are evidence of a Pan-African suture zone within the northern Shackleton Range. This suture marks the site of a palaeo-subduction zone that likely continues to the Herbert Mountains, where ophiolitic rocks of Neoproterozoic age testify to an ocean basin that was closed during Pan-African collision. The garnet-bearing ultramafic rocks in the Shackleton Range are the first known example of eclogite facies metamorphism in Antarctica that is related to the collision of East and West Gondwana and the first example of Pan-African eclogite facies ultramafic rocks worldwide. Eclogites in the Lanterman Range of the Transantarctic Mountains formed during subduction of the palaeo-Pacific beneath the East Antarctic craton.     

REVIEWS OF GEOGRAPHIC SOFTWARE

Reviews of geographic software in this article: DEMO-GRAPHICS: WORLD POPULATIONS AND PROJECTIONS. ESP GAUSS. CEMODEL S. Damus LIMDEP. William H. Greene MICROSTAT 4.1 OTIS PCIPS. (Personal Computer Image Processing System) . H.J. Meyers and R. Bernstein. REGRESSION ANALYSIS OF TIME SERIES (RATS) SPSS/PC+ URBAN DATA MANAGEMENT SOFTWARE (UDMS)     

The Lower Permian Wasp Head Formation,Sydney Basin: high‐latitude,shallow marine sedimentation following the late Asselian to early Sakmarian glacial event in eastern Australia

The Lower Permian Wasp Head Formation (early to middle Sakmarian) is a ～95 m thick unit that was deposited during the transition to a non‐glacial period following the late Asselian to early Sakmarian glacial event in eastern Australia. This shallow marine, sandstone‐dominated unit can be subdivided into six facies associations. (i) The marine sediment gravity flow facies association consists of breccias and conglomerates deposited in upper shoreface water depths. (ii) Upper shoreface deposits consist of cross‐stratified, conglomeratic sandstones with an impoverished expression of the Skolithos Ichnofacies. (iii) Middle shoreface deposits consist of hummocky cross‐stratified sandstones with a trace fossil assemblage that represents the Skolithos Ichnofacies. (iv) Lower shoreface deposits are similar to middle shoreface deposits, but contain more pervasive bioturbation and a distal expression of the Skolithos Ichnofacies to a proximal expression of the Cruziana Ichnofacies. (v) Delta‐influenced, lower shoreface‐offshore transition deposits are distinguished by sparsely bioturbated carbonaceous mudstone drapes within a variety of shoreface and offshore deposits. Trace fossil assemblages represent distal expressions of the Skolithos Ichnofacies to stressed, proximal expressions of the Cruziana Ichnofacies. Impoverished trace fossil assemblages record variable and episodic environmental stresses possibly caused by fluctuations in sedimentation rates, substrate consistencies, salinity, oxygen levels, turbidity and other physio‐chemical stresses characteristic of deltaic conditions. (vi) The offshore transition‐offshore facies association consists of mudstone and admixed sandstone and mudstone with pervasive bioturbation and an archetypal to distal expression of the Cruziana Ichnofacies. The lowermost ～50 m of the formation consists of a single deepening upward cycle formed as the basin transitioned from glacioisostatic rebound following the Asselian to early Sakmarian glacial to a regime dominated by regional extensional subsidence without significant glacial influence. The upper ～45 m of the formation can be subdivided into three shallowing upward cycles (parasequences) that formed in the aftermath of rapid, possibly glacioeustatic, rises in relative sea‐level or due to autocyclic progradation patterns. The shift to a parasequence‐dominated architecture and progressive decrease in ice‐rafted debris upwards through the succession records the release from glacioisostatic rebound and amelioration of climate that accompanied the transition to broadly non‐glacial conditions.     

Geochemistry of S-type granitic rocks from the reversely zoned Castelo Branco pluton (central Portugal)

The zoned pluton from Castelo Branco consists of Variscan peraluminous S-type granitic rocks. A muscovite>biotite granite in the pluton's core is surrounded successively by biotite>muscovite granodiorite, porphyritic biotite>muscovite granodiorite grading to biotite=muscovite granite, and finally by muscovite>biotite granite. ID-TIMS U–Pb ages for zircon and monazite indicate that all phases of the pluton formed at 310 ± 1 Ma. Whole-rock analyses show slight variation in ⁸⁷Sr/⁸⁶Sr_310 Ma between 0.708 and 0.712, Nd_310 Ma values between − 1 and − 4 and δ¹⁸O values between 12.2 and 13.6. These geological, mineralogical, geochemical and isotopic data indicate a crustal origin of the suite, probably from partial melting of heterogeneous Early Paleozoic pelitic country rock. In detail there is evidence for derivation from different sources, but also fractional crystallization linking some of internal plutonic phases. Least-squares analysis of major elements and modelling of trace elements indicate that the porphyritic granodiorite and biotite=muscovite granite were derived from the granodiorite magma by fractional crystallization of plagioclase, quartz, biotite and ilmenite. By contrast variation diagrams of major and trace elements in biotite and muscovite, the behaviours of Ba in microcline and whole-rock δ¹⁸O, the REE patterns of rocks and isotopic data indicate that both muscovite-dominant granites were probably originated by two distinct pulses of granite magma.